Product ID:7805 GLOSS BLACK, FAST DRY ACRYLIC ENAMEL 7
MSDS Date:06/01/1991
FSC:8010
NIIN:00N028880
MSDS Number: BMYLQ

MARTIN-SENOUR CO

101 PROSPECT AVE NW
CLEVELAND, OH 44115
US

Emergency Phone: 216-566-2917

Info Phone: 216-566-2902

Cage: MART2

SHERWIN-WILLIAMS CO THE

CLEVELAND, OH 44115-1042 US

Telephone: 800-251-2486/216-566-2242

Cage: 54636

ETHANOL, 2-BUTOXY-, ACETATE; (2-BUTOXYETHYL ACETATE). VP

CAS: 112-07-2

RTECS: KJ8925000

Fraction By Weight: 2%

ACGIH TLV: 50 PPM (MFR)

CARBON BLACK

CAS: 1333-86-4

RTECS: FF5800000

Fraction By Weight: 2%

OSHA PEL 3.5 MG/M3

ACGIH TLV: 3.5 MG/M3

CONTAINING METHYL ETHYL KETONE MAY ALSO

RTECS: 9999999ZZ

DEPRESSURIZE CONTAINER. DISPOSE OF IN ACCORDANCE

RTECS: 9999999ZZ

PROC. CONTENTS UNDER PRESS.DO NOT PUNCTURE,

RTECS: 9999999ZZ

RADIATORS, STOVES, HOT H*2O, & OTHER HEAT SOURCES

RTECS: 9999999ZZ

KEEP OUT OF REACH OF CHILDREN. INTENTIONAL MISUSE

RTECS: 9999999ZZ

DRIED FILM,WEAR A NIOSH/MSHA APPRVD PARTICULATE

RTECS: 9999999ZZ

180.0.

CAS: 67-64-1

RTECS: AL3150000

Fraction By Weight: 31%

OSHA PEL 1000PPM

ACGIH TLV: 750PPM/1000STEL;9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

760.0.

CAS: 74-98-6

RTECS: TX2275000

Fraction By Weight: 10%

OSHA PEL 1000 PPM

ACGIH TLV: SIMPLE ASPHYXIANT

760.0.

CAS: 75-28-5

RTECS: TZ4300000

Fraction By Weight: 14%

2.0.

CAS: 64742-47-8

Fraction By Weight: 2%

OSHA PEL 100 PPM (MFR)

ACGIH TLV: 100 PPM (MFR)

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 11%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

7.1.

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: 2%

OSHA PEL 100 PPM;125 PPM STEL

ACGIH TLV: 100 PPM;125 PPM STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

5.9.

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 12%

OSHA PEL 100 PPM;150 PPM STEL

ACGIH TLV: 100 PPM;150 PPM STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

3.8.

CAS: 64742-95-6

Fraction By Weight: 2%

ACGIH TLV: 100 PPM (MFR)

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:(ACUTE)IRRIT OF EYES,SKIN & RESP
SYS.MAY CAUSE NERVOUS SYS DEPRESS. EXTREME OVEREXP MAY RSLT IN
UNCON & POSS DEATH. (CHRONIC) PRLNGD OVEREXP TO SOLV INGREDS IN
INGREDS SECTION MAY CAUSE ADVERSE EFTS T O LIVER,URINARY, BLOOD
FORMING, NERVOUS, CARDIO-VASCULAR, & REPROD SYS.REPORTS HAVE ASSOC
RPTD/PRLNGD OVEREXP(SUPP DATA)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HEADACHE, DIZZ, NAUS, AND LOSS OF COORDINATION
ARE INDICATIONS OF EXCESSIVE EXPOS TO VAPORS OR SPRAY MISTS.
REDNESS AND ITCHING OR BURNING SENSATION MAY INDICATE EYE OR
EXCESSIVE SKIN EXPOS. TOLUENE, CAS NO. 108-88-3 APPEARS ON THE
NAVY LISTING OF OCCUPATIONAL REPRODUCTIVE HAZARDS. SEEK
CONSULTATION FROM (MED COND)
Medical Cond Aggravated by Exposure:SIGNS/SYMP: HEALTH PROFESSIONALS
CONCERNING LATEST HAZARD LIS INFORMATION AND SAFE HANDLING AND
EXPOSURE RECOMMENDAIONS .

First Aid:INHALATION: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP
WARM AND QUIET. SKIN: WASH AFFECTED AREA THORO WITH SOAP AND WATER.
REMOVE CONTAM CLOTHING AND LAUNDER BEFORE RE-USE. EYES: FLUSH EYES
WITH LA RGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MED ATTN.
INGESTION: NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
DO NOT INDUCE VOMIT. GIVE SEVERAL GLASSES OF H*2O. SEEK MED ATTN.

Flash Point Method:PMCC
Flash Point:<0F,<-18C
Lower Limits:0.7%
Upper Limits:6.0%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT
EQUIP.H*2O SPRAY MAY BE INEFT. IF H*2O USED,FOG NOZ PREFERABLE.
H*2O MAY BE USED TO COOL CLSD CNTNRS (SUPP DATA)
Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM
HEAT, ELEC EQUIP, SPARKS, & OPEN FLAME. CLSD CNTNRS MAY EXPLO WHEN
EXPOS TO EXTREME HEAT. APPLIC TO HOT SURFS (SUPP DATA)

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:CONTENTS ARE EXTREMELY FLAMMABLE. KEEP
AWAY FROM HEAT, SPARKS & OPEN FLAME. VAPS WILL ACCUMULATE READILY &
MAY IGNITE EXPLOSIVELY.
Other Precautions:DURING USE & UNTIL ALL VAPS ARE GONE: KEEP AREA
VENT-DO NOT SMOKE-EXTING ALL FLAMES, PILOT LIGHTS, & HEATERS-TURN
OFF STOVES, ELEC TOOLS & APPLIANCES, & ANY OTHER SOURCES OF IGNIT.
CONSULT NFPA CODE. USE APPRVD BONDING & GROUNDING (ING 13)

Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW
APPLIC LIMITS BY VENT, WEAR NIOSH/MSHA APPRVD PROPERLY FITTED ORG
VAP/PARTICULATE RESP FOR PROT AGAINST MATLS IN INGREDS SECTION.
WHEN SANDING, WIREBRUSHIN G, ABRADING, BURNING/WELDING (ING 16)
Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS IS MAINTAINED
< APPLIC EXPOS LIM. REFER TO OSHA STD 1910.94, 107,108.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:USE ONLY W/ADEQ VENT. AVOID BRTHG VAP & SPRAY
MIST. AVOID CONT W/SKIN & EYES. WASH HANDS AFTER USING.
Supplemental Safety and Health
FIRE FIGHT PROC: TO PVNT PRESS BUILD-UP & POSS AUTOIGNIT/EXPLO WHEN
EXPOS TO EXTREME HEAT. EXPLO HAZ: REQS SPECIAL PREC. DURING EMER
CNDTNS OVEREXP TO DECOMP PRODS MAY CAUSE HLTH HAZ. SYMP MAY NOT BE
IMMED APPARENT. OBTAIN MED ATTN. HLTH HAZ: TO SOLV WITH PERMANENT
BRAIN AND NERVOUS SYSTEM DAMAGE.

HCC:V3
Boiling Pt:B.P. Text:<0F,<-18C
Vapor Pres:SEE INGRED
Vapor Density:HVR/AIR
Evaporation Rate & Reference:FASTER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:>75

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE, OXIDES OF METALS IN INGREDIENTS SECTION.

Waste Disposal Methods:WASTE FROM PROD MAY BE HAZ AS DEFINED UNDER RCRA
40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE
APPLIC EPA HAZ WASTE NUMBERS. WASTE FROM PRODS CONTAINING
LEAD/CHROMATE MUST ALSO BE TES TED FOR EXTRACTABILITY. WASTE FROM
PRODS (ING 11)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.